WebDec 1, 2024 · After 1 h of stirring, the phosphoranimine monomer Cl 3 P = NSiMe 3 was obtained as a white suspension. Then, PCl 5 was dissolved in dry p-chlorotoluene with a concentration of ∼2 mol/L and 10 mL of the freshly prepared solution was quickly added to the monomer/p-chlorotoluene solution. The resultant mixture was stirred overnight at 25 °C. WebOne option to circumvent this is the combination of the cationic polymerisation of Cl 3 PNSiMe 3 with a second block using a phosphoranimine of the type ClR 2 P N-SiMe 3, resulting in one “tunable” block of [NPCl 2] n, with its wide array of possible substituents, followed by a polyalky/arylphosphazene block. 26
Synthesis and Reactivity of Phosphine-Stabilized …
WebDec 1, 2006 · Synthesis and reactivity of phosphine-stabilized phosphoranimine cations, [R3P x PR'2=NSiMe3]+. Huynh K, Lough AJ, Forgeron MA, Bendle M, Soto AP, Wasylishen RE, Manners I. J Am Chem Soc, 131(22):7905-7916, 01 Jun 2009 Cited by: 3 articles PMID: 19449868. Cyclotetraphosphinophosphonium ions: synthesis, structures, and … WebStructure, properties, spectra, suppliers and links for: trichloro(trimethylsilyl)phosphoranimine. im on one remix
phosphinimine H2NP ChemSpider
WebDevelopment of nanocarrier-based drug delivery systems is a major breakthrough in pharmacology, promising targeted delivery and reduction in drug toxicity. WebSep 22, 2006 · Complete conversion of a phosphoranimine monomer was observed within 2 hours under mild conditions (ca. 100°C) in solution polymerization with SbCl 5. Poly[bis(trifluoroethoxy)phosphazenes] of molecular weight M n = 10,000 to 50,000 were obtained with low to moderate polydispersities ( M w / M n = 1.2 to 2.5) and were … WebA colorless poisonous war gas (PH 3) with a characteristic garliclike odor; also the active agent in some rodenticides; formed in small quantities in the putrefaction of organic … imon shampoo